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Phosphorus, 15 waxy white (yellae cut), reid (granules centre left, chunk centre richt), an violet phosphorus
Phosphorus Pronunciation (FOS -fər-əs Appearance colourless, waxy white, yellae, scarlet, reid, violet, black Standard atomic weight A r, std (P) 7001309737619980000♠ 30.973761 998 (5)[ 1] Phosphorus in the periodic cairt
Atomic nummer (Z ) 15 Group group 15 (pnictogens) Period period 3 Block p-block Element category Reactive nonmetal Electron confeeguration [Ne ] 3s2 3p3 Electrons per shell 2, 8, 5 Pheesical properties Phase at STP solit Density (near r.t. ) (white) 1.823, (red) ≈ 2.2 – 2.34, (violet) 2.36, (black) 2.69 g/cm3 Treeple pynt Heat o fusion (white) 0.66 kJ/mol Heat o vapourisation (white) 12.4 kJ/mol Molar heat capacity (white) Vapour pressur
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
279
307
342
388
453
549
Vapour pressur
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
455
489
529
576
635
704
Atomic properties Oxidation states −3 [ 2] [ 3] +3 +5 acidic oxide)Electronegativity Pauling scale: 2.19 Ionisation energies Covalent radius 107±3 pm Van der Waals radius 180 pm Colour lines in a spectral range Spectral lines o phosphorusIther properties Naitural occurrence primordial Creestal structur simple triclinic Thermal conductivity (white) 0.236, (black) 12.1 W/(m·K) Magnetic orderin (white, red, violet, black) diamagnetic [ 4] Bulk modulus (white) 5, (reid) 11 GPa CAS Nummer 7723-14-0 (reid) History Diskivery Hennig Brand (1669) Recognized as an element bi Antoine Lavoisier [ 5] Main isotopes o phosphorus
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References
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↑ Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)" . Pure and Applied Chemistry 88 (3): 265–91. doi :10.1515/pac-2015-0305 ↑ Wang, Yuzhong; Xie, Yaoming; Wei, Pingrong; King, R. Bruce; Schaefer, Iii; Schleyer, Paul v. R.; Robinson, Gregory H. (2008). "Carbene-Stabilized Diphosphorus". Journal of the American Chemical Society . 130 (45): 14970–1. doi :10.1021/ja807828t . PMID 18937460 . ↑ Ellis, Bobby D.; MacDonald, Charles L. B. (2006). "Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds". Inorganic Chemistry . 45 (17): 6864–74. doi :10.1021/ic060186o . PMID 16903744 . ↑ Magnetic susceptibility of the elements and inorganic compounds , in Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5 ↑ cf. "Memoir on Combustion in General " Mémoires de l'Académie Royale des Sciences 1777, 592–600. from Henry Marshall Leicester and Herbert S. Klickstein, A Source Book in Chemistry 1400–1900 (New York: McGraw Hill, 1952)
↑ webelements ↑ Ellis, Bobby D.; MacDonald, Charles L. B. (2006). "Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds". Inorganic Chemistry . 45 (17): 6864–74. doi :10.1021/ic060186o . PMID 16903744 .
